We don't know of any S-class Fire jutsu's as they haven't shown any.
Amatersu is probably the most powerful fire jutsu we have seen and it is not classified because its related to a blood limit which are never classified rank wise.
I think someone else mentioned it but yes Karyuu Endan is B rank Fire jutsu
Nagato yea could use all 5 elements but as afro said but also the 7 unique jutsu' related to the Rinnengan which the Pain system he developed seemed to use 1 of each.
Oddly enough God realm seemed to use a water based jutsu in the rain detection field he put up around Amegakure so maybe the jutsu limit of the Pain system had more flexibility for God realm.
With 7 other worldy powers using elemental jutsu's by comparisons seems weak so no he didnt use any elemental jutsu's in Konoha.






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